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Request an estimateFor practical applications Cu(I) π complexation adsorption demands both a high performance and a good stability In this work we simultaneously incorporated copper and vanadium into a typical metal–organic framework (MOF) of MIL 101 Thanks to the assistance of V selective reduction of Cu(II) to Cu(I) was efficiently realized at a low temperature of 250 C
Highly selective separation of vanadium over iron 25 01 2017 In general most vanadium in stone coal exists in the crystal lattice of the aluminosilicate minerals and isomorphically replaces Al (III) in vanadium bearing mica group minerals (such as illite muscovite and biotite) so it is difficult to extract vanadium from stone coal
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Selective Separation and Extraction of Vanadium IV and May 15 2019 The maximum vanadium extraction was 96 70 one stage using the mixture of Cyanex272 and N235 • The formation of hydrogen bond N H O P is confirmed to enhance the vanadium extraction A
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@article{osti_1333009 title = {Selective separation of trivalent f ions using 1 10 phenanthroline 2 9 dicarboxamide ligands in ionic liquids} author = {Dehaudt Jeremy and Williams Neil J and Shkrob Ilya A and Luo Huimin and Dai Sheng} abstractNote = {1 10 Phenanthroline 2 9 dicarboxamide complexants decorated with alkyl chains and imidazolium cations have been studied for extraction
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Daejon (22 8km2) is Protean's flagship asset with further exploration ground held at Miwon (16 6km2) and Gwesan (24 8km2) Daejon is a unique sediment hosted shale slate bed vanadium project which has the potential to produce high purity vanadium pentoxide (V2O5)
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(2018) Extraction of vanadium from V Cr bearing reduced residue by selective oxidation combined with alkaline leaching Canadian Metallurgical Quarterly: Vol 57 No 4 pp 434 438
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Vanadium was separated from elements that do not form anionic complexes with malonic acid by selective extraction from those that form weak complexes by washing the organic extract with water and from metals that form strong malonato complexes by selective stripping with hydrochloric nitric or
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Extract uranium and vanadium whether simultaneously (followed by selective stripping) or successively [8] In Egypt a combined occurrenceof U V has been discovered at adi El SahuW area (Sinai) where a mineralization of the two minerals carnotite [K 2(UO 2) 2(VO
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Selective carbothermic reduction and smelting (SCRS) has fewer less energy intensive beneficiation steps Recovers iron chromium manganese vanadium silicon titanium barium aluminum magnesium or calcium as metals metal oxides (such MnO2 and TiO2) or metal sulfide (BaSO4) Can be applied to beneficiate current mining is a useful product
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Selective oxidation of Vanadium prior to Iron and Know LKAB in northern Sweden have vanadium and titanium dissolved in the magnetite [2] The ore consists of After cooling the slag is crushed and separated into two frac tions 1839 in iron produced from Taberg ore Sm land Sweden [5]
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The solvent extraction behaviour of vanadium(V) from hydrochloric acid solutions has been investigated using 2‐ethylhexyl phosphonic acid mono‐2‐ethylhexyl ester (EHEHPA ≡ HX) in kerosene as an extra
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Selective catalytic reduction (SCR) catalyst To recover vanadium (V) and tungsten (W) from spent SCR catalyst leach liquors from hydrometallurgical processing were utilized to develop a proper methodology for extraction and possible separation of vanadium and tungsten from each other
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Oct 24 2019 The separation of vanadium (V) and molybdenum (VI) was studied by co extraction with an aqueous two phase system formed by PEG2000 + sodium sulfate + water and by selective stripping with another aqueous two phase system formed by ammonium sulfate solution and PEG2000 phase loaded vanadium and molybdenum The effect of aqueous pH concentration of vanadium and
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Abstract In the process of precipitating ammonium polyvanadate (APV) to produce vanadium pentoxide in Pan steel in China rest waste water usually contains about 24~333mg L V(V) 2~100g L Cr(VI) 20~500mg L Si(IV) and 20~100g L Na 2 SO 4 In order to recover valuable and also toxic metal ions contained in the waste water effective extraction method of using anion exchange resin was
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May 25 2020 We demonstrate highly selective vanadium removal in the presence of various competing anions (i e fluoride bromide nitrate and sulfate) Surface elemental analysis reveals significant correlation between PVFc moieties and vanadium‐rich regions after adsorption corroborating the central role of PVFc modulation on vanadium separation
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Selective leaching process could be achieved by enhancing the electric filed in the alkaline medium Therefore in this paper vanadium and chromium were separated and recovered by a two step leaching process: electro oxidation leaching of vanadium and H 2 O 2 as well as oxidation leaching of chromium in an alkaline medium
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The ore which contains 57 5 Fe 0 66 V and 16 6 TiO 2 was subjected to selective reduction smelting so that most of the iron reported to the metal phase and the vanadium and titanium to the slag phase The iron had a purity of 99 The slag contained between 935 FeO 3146 TiO 2 and 1 21 6 V Over 98 of the titanium and vanadium
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China After preprocessing by selective oxidation of V(IV) to V(V) the composition of its acid leaching solution is listed in Table 1 Therefore the solutions containing 5 g L V(V) and 10 g L Cr(III) were used in the experiments and prepared in the laboratory using sodium metavanadate and basic chromic sulfate A dithiocarbamate (R1R2NCS2
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Abstract: A novel method for the separation and reclamation of vanadium and chromium from acidic solution was proposed The principle for the separation is based on selective complexation In specific V(V) can be complexated by dithiocarbamate to form VO(R 1 R 2 NCS 2) 3 precipitate leaving Cr(III) remained in the acidic solution Then the reclamation of V and Cr from VO(R 1 R 2 NCS 2) 3
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A recent study indicated that a selective leaching process could be achieved by enhancing the electric filed in the alkaline medium Therefore in this paper vanadium and chromium were separated and recovered by a two step leaching process: electro oxidation leaching of vanadium and H 2 O 2 as well as oxidation leaching of chromium in an
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Novel technology for selective separation and extraction of vanadium(IV) and manganese(II) from co leaching solution of roasted stone coal and pyrolusite via solvent extraction was used to study the extraction of vanadium(IV) and manganese(II) and many technical conditions have also been optimized Countercurrent experiments were conducted to verify the results of the experiments The results
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The solvent extraction of vanadium and molybdenum by tri n octylmethylammonium chloride (TOMAC) from neutral solutions was studied and it was found that vanadium was extracted preferentially by an anion exchange mechanism The pentavalent vanadyl anion in the organic solution was found to be reduced to the form of tetra or trivalent cations by contact with an aqueous solution containing a
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Feb 15 2007 The selective extraction results using series contacts of solution mixtures with resins further demonstrated the feasibility of D 2 EHPA‐immobilized Amberlite XAD‐4 resin for the separation of Mo V mixed ion solution After only seven batches of contacts the relative ion concentration of V ion increased from 67 to than 96 while the
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Selective Leaching of Vanadium from Roasted Stone Coal by Dilute Sulfuric Acid Dephosphorization Two Stage Pressure Acid Leaching Jun Huang 1 3 Yimin Zhang 1 2 3 Jing Huang 1 2 3 Tao Liu 1 2 3 Zhenlei Cai 1 2 3 and Nannan Xue 1 2 1 College of Resources and Environmental Engineering Wuhan University of Science and Technology
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The variation of pH (selective extraction) and selective stripping were investigated as methods of separation of Mo(VI) and V(V) The latter method was found inefficient for separations from HNO 3 solutions (pH = 1 0) except supplemented with selective stripping (back extraction with 2 0 mol L −1 H 2 SO 4 14 5 mol L −1 NH 4 OH)
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Feb 15 2007 (2003) Solvent Extraction and Separation of Vanadium (V) from Multivalent Metal Chloride Solutions by Cyanex 923 Solvent Extraction and Ion Exchange: Vol 21 No 4 pp 573 589
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Application of Polymer Inclusion Membrane for Selective Extraction and On line Separation Determination in Flow Injection Analysis System of Vanadium(V) Mohammad Reza Yaftian Department of Chemistry Faculty of Science University of Zanjan Zanjan Iran School of Chemistry The University of Melbourne Victoria Australia Sabbatical Leave Report
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Electrochemical platform for selective recovery of toxic metal Limited access to clean water is a challenge in many regions of the world This problem can be exacerbated by the industrial release of toxic heavy metal pollutants into the environment
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Abstract Vanadium is known to produce solutions of complex speciation as a function of vanadium concentration and pH Various solvent extractants have been tested for vanadium recovery from acidic leachates This research assesses the selectivity of extraction of vanadium (V IV) over iron (III II) in sulphate media using phosphinic acid (Cyanex 272) phosphonic acid (Ionquest 801
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Apr 15 2015 The loaded organic containing Al 730 mg L Fe 262 mg L and Ti 155 mg L was washed first with 5 (NH 4) 2 CO 3 for selective stripping of Ti from Fe and Al After the removal of Ti Fe was stripped from organic phase by washing it first with10 ml of
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